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Material properties (thermodynamics) : ウィキペディア英語版
Material properties (thermodynamics)

The thermodynamic properties of materials are intensive thermodynamic parameters which are specific to a given material. Each is directly related to a second order differential of a thermodynamic potential. Examples for a simple 1-component system are:
* Compressibility (or its inverse, the bulk modulus)
:
* Isothermal compressibility
::\beta_T=-\frac\left(\frac\right)_T
\quad = -\frac\,\frac
:
* Adiabatic compressibility
::\beta_S=-\frac\left(\frac\right)_S
\quad = -\frac\,\frac
* Specific heat (Note - the extensive analog is the heat capacity)
:
* Specific heat at constant pressure
::c_P=\frac\left(\frac\right)_P
\quad = -\frac\,\frac
:
* Specific heat at constant volume
::c_V=\frac\left(\frac\right)_V
\quad = -\frac\,\frac
* Coefficient of thermal expansion
::\alpha=\frac\left(\frac\right)_P
\quad = \frac\,\frac
where ''P''  is pressure, ''V''  is volume, ''T''  is temperature, ''S''  is entropy, and ''N''  is the number of particles.
For a single component system, only three second derivatives are needed in order to derive all others, and so only three material properties are needed to derive all others. For a single component system, the "standard" three parameters are the isothermal compressibility \beta_T, the specific heat at constant pressure c_P, and the coefficient of thermal expansion \alpha.
For example, the following equations are true:
:c_P=c_V+\frac
:\beta_T=\beta_S+\frac
The three "standard" properties are in fact the three possible second derivatives of the Gibbs free energy with respect to temperature and pressure.
==Sources==
The Dortmund Data Bank is a factual data bank for thermodynamic and thermophysical data.
See thermodynamic databases for pure substances.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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